Taken from EP36 of (Actually) Abridged:
Riding high off of accidentally defeating Team Rocket in a complete fluke 4 episodes prior, Misty’s Psyduck enters it’s first real Pokemon Battle against an enemy trainer.
(PS: I don’t consider EP 32 a real battle because Team Rocket never even bothers to attack Psyduck - they’re just dumbfounded by it the entire time)
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